Etching of As- and P-based III-V semiconductors in a planar inductively coupled BCl3/Ar plasma

A parametric study of the etch characteristics of Ga-based (GaAs, GaSb, and AlGaAs) and In-based (InGaP, InP, InAs, and InGaAsP) compound semiconductors in BCl3/Ar planar inductively coupled plasmas (ICPs) was performed. The Ga-based materials etched at significantly higher rates, as expected from the higher volatilities of the As, Ga, and Al trichloride, etch products relative to InCl3. The ratio of BCl3 to Ar proved critical in determining the anisotropy of the etching for GaAs and AlGaAs, through its effect on sidewall passivation. The etched features in In-based materials tended to have sloped sidewalls and much rougher surfaces than for GaAs and AlGaAs. The etched surfaces of both AlGaAs and GaAs have comparable root-mean-square (RMS) roughness and similar stoichiometry to their unetched control samples, while the surfaces of In-based materials are degraded by the etching. The practical effect of the Ar addition is found to be the ability to operate the ICP source over a broader range of pressures and to still maintain acceptable etch rates.