Synthesis, structure, and mechanism of half-sandwich ruthenium complexes based on ortho-carborane-1,2-dithiolate ligand and alkyne alcohol

被引：6
|
作者：
Hu, J. R. [1 ]
Zhang, W. J. [1 ]
Liu, L. H. [1 ]
Peng, H. N. [1 ]
机构：
[1] Shangrao Normal Univ, Key Lab Appl Organ Chem, Higher Inst Jiangxi Prov, Sch Chem & Chem Engn, Shangrao 334001, Jiangxi, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 12期
基金：
中国国家自然科学基金;
关键词：
CHELATING 1,2-DICARBA-CLOSO-DODECABORANE-1,2-DICHALCOGENOLATE LIGAND; B-H ACTIVATION; TRANSITION-METAL-COMPLEXES; BONDS; ETHYNYLFERROCENE; DERIVATIVES; ACETYLENE;
D O I：
10.1134/S1070328414120057
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel complex (p-cymene)Ru(S2C2B10H9)((OH)H(2)CCCHFc) center dot 0.5CH(2)Cl(2) (Fc = ferrocenyl) based on the ortho-carborane-1,2-dithiolate ligand and alkyne alcohol has been synthesized successfully and characterized by IR, NMR, MS, elemental analysis and single-crystal X-ray diffraction (CIF file CCDC no. 1007680). The complex crystallizes in monoclinic system, space group C2/c with a = 27.1243(13), b = 11.8161(6), c = 20.8360(11) , beta = 108.689(3)A degrees, C51H74B20O2S4Cl2Fe2Ru2, Mr = 1448.28, V = 6325.9(6) (3), rho (c) = 1.521 g/cm(3), Z = 4, F(000) = 2936, mu(MoK (alpha)) = 1.174 mm(-1), R = 0.0551 and wR = 0.1518 for 5329 observed reflections (I > 2 sigma(I)). Structural analysis shows that there are metal-induced B-H activation, the generation of a Ru-B bond, and the coordination of the C=C bond.
引用
收藏
页码：954 / 958
页数：5
相关论文
共 50 条
  • [1] Synthesis, structure, and mechanism of half-sandwich ruthenium complexes based on ortho-carborane-1,2-dithiolate ligand and alkyne alcohol
    J. R. Hu
    W. J. Zhang
    L. H. Liu
    H. N. Peng
    Russian Journal of Coordination Chemistry, 2014, 40 : 954 - 958
  • [2] SYNTHESIS, STRUCTURE, AND MECHANISM OF HALF-SANDWICH RUTHENIUM COMPLEX CONTAINING ORTHO-CARBORANE-1,2-DITHIOLATE LIGAND AND 1-PHENYL-2-PROPYN-1-OL
    Hu, J. R.
    Zhao, S. Q.
    Wang, J. H.
    Sun, S. Q.
    Miao, C. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2023, 64 (12) : 2343 - 2350
  • [3] Half-sandwich rhodium complexes containing both N-heterocyclic carbene and ortho-carborane-1,2-dithiolate ligands
    Xiao, Xu-Qiong
    Jin, Guo-Xin
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (02) : 316 - 320
  • [4] Stepwise and Selective Carborane Substitution in the B(3,6) Positions of a 16e CpCo Half-Sandwich Complex Containing a Chelating ortho-Carborane-1,2-dithiolate Ligand
    Li, Yuguang
    Jiang, Qibai
    Zhang, Xiaolei
    Li, Yizhi
    Yan, Hong
    Bregadze, Vladimir I.
    INORGANIC CHEMISTRY, 2010, 49 (08) : 3911 - 3917
  • [5] Synthesis, Crystal Structure, and Mechanism of Formation of the Half-Sandwich Ruthenium Complexes Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and PhCH(OH)C≡CH
    J. R. Hu
    J. H. Wang
    J. Y. Jin
    J. S. Liu
    S. Q. Sun
    C. P. Miao
    Russian Journal of Inorganic Chemistry, 2023, 68 : 1956 - 1962
  • [6] Synthesis, Crystal Structure, and Mechanism of Formation of the Half-Sandwich Ruthenium Complexes Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and PhCH(OH)C≡CH
    Hu, J. R.
    Wang, J. H.
    Jin, J. Y.
    Liu, J. S.
    Sun, S. Q.
    Miao, C. P.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 68 (14) : 1956 - 1962
  • [7] Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol
    J. R. Hu
    S. Q. Zhao
    J. H. Wang
    S. Q. Sun
    C. P. Miao
    Journal of Structural Chemistry, 2023, 64 : 2343 - 2350
  • [8] Synthesis and Structural Characterization of the Ruthenium Complexes Based on ortho-Carborane-1,2-diselenolate Ligand and Terminal Alkynone
    J. R. Hu
    J. H. Wang
    Russian Journal of Inorganic Chemistry, 2022, 67 : 1739 - 1744
  • [9] Synthesis and Structural Characterization of the Ruthenium Complexes Based on ortho-Carborane-1,2-diselenolate Ligand and Terminal Alkynone
    Hu, J. R.
    Wang, J. H.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 67 (11) : 1739 - 1744
  • [10] Synthesis and characterization of binuclear half-sandwich metal (Co, Ir and Ru) complexes containing ancillary ortho-carborane-1,2-dithiolato ligands
    Liu, Shuang
    Zhang, Jiasheng
    Wang, Xin
    Jin, Guo-Xin
    DALTON TRANSACTIONS, 2006, (44) : 5225 - 5230
12345