Iodine-Catalyzed Regioselective 2-Sulfonylation of Indoles with Sodium Sulfinates

被引：206
|
作者：
Xiao, Fuhong [1 ]
Chen, Hui [1 ]
Xie, Hao [1 ]
Chen, Shuqing [1 ]
Yang, Luo [1 ]
Deng, Guo-Jun [1 ,2 ]
机构：
[1] Xiangtan Univ, Coll Chem, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100080, Peoples R China
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 01期
基金：
高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词：
UNSYMMETRICAL DIARYL SULFONES; FRIEDEL-CRAFTS SULFONYLATION; AROMATIC-COMPOUNDS; EFFICIENT SYNTHESIS; VINYL SULFONES; ARYL SULFONES; ACID SALTS; METAL-FREE; OXIDATION; SULFIDES;
D O I：
10.1021/ol402987u
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Iodine-catalyzed selective 2-arylsulfonyl indole formation from indoles and sodium sulfinates is disclosed. Various substituted 2-arylsulfonyl indoles were obtained in one pot in the absence of metal catalyst at room temperature under air.
引用
收藏
页码：50 / 53
页数：4
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