Synergy of Anodic Oxidation and Cathodic Reduction Leads to Electrochemical C-H Halogenation

被引：76

作者：

Zhou, Zhilin ^{[1
]}

Yuan, Yong ^{[2
]}

Cao, Yangmin ^{[1
]}

Qiao, Jin ^{[1
]}

Yao, Anjin ^{[1
]}

Zhao, Jing ^{[1
]}

Zuo, Wanqing ^{[1
]}

Chen, Wenjie ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Jiangxi Normal Univ, Natl Res Ctr Carbohydrate Synth, Nanchang 330022, Jiangxi, Peoples R China

[2] Wuhan Univ, Coll Chem & Mol Sci, Inst Adv Studies, Wuhan 430072, Hubei, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2019年 / 37卷 / 06期

基金：

中国国家自然科学基金;

关键词：

BOND FORMATION; METAL-FREE; ORGANIC ELECTROSYNTHESIS; FUNCTIONALIZATION; BROMINATION; CYCLIZATION; EFFICIENT; CATALYST; ALKENES; REAGENT;

D O I：

10.1002/cjoc.201900091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We herein uncovered an electrochemical C-H halogenation protocol that synergistically combines anodic oxidation and cathodic reduction for C-X bond formation. The reaction was demonstrated under exogenous-oxidant-free conditions. Moreover, this is the first example of activating CBr4, CHBr3, and CCl3Br under electrochemical conditions.

引用

页码：611 / 615

页数：5

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