Chiral Lewis Acid Rare-Earth Metal Complexes in Enantioselective Catalysis

被引：13
|
作者：
Feng, Xiaoming [1 ]
Wang, Zhen [1 ,2 ]
Liu, Xiaohua
机构：
[1] Sichuan Univ, Chengdu, Sichuan, Peoples R China
[2] Chongqing Univ, Chongqing, Peoples R China
来源：
CHIRAL LEWIS ACIDS | 2018年 / 62卷
关键词：
Asymmetric catalysis; Chiral bipyridine alcohol; Chiral bis (oxazolinyl)pyridine; Chiral ligand; Chiral N; N'-dioxide; Lewis acid; Rareearth metal; DIELS-ALDER REACTION; ASYMMETRIC CONJUGATE ADDITION; FRIEDEL-CRAFTS ALKYLATIONS; HIGHLY EFFICIENT SYNTHESIS; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; UNPROTECTED 3-SUBSTITUTED OXINDOLES; 1,3-DIPOLAR CYCLOADDITION REACTIONS; BETA-KETO-ESTERS; KINETIC RESOLUTION; MICHAEL ADDITION;
D O I：
10.1007/3418_2017_1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The progress made over the past two decades in asymmetric catalysis, focusing on chiral Lewis acid complexes of rare-earth metal, is reviewed. The applications of several different catalytic systems of chiral Lewis acid complexes in various asymmetric reactions have been discussed: (1) asymmetric aldol reaction, (2) asymmetric Mannich reaction, (3) asymmetric Michael reaction, (4) asymmetric Friedel-Crafts reaction, (5) asymmetric homologation of carbonyl compounds with alpha-diazoesters, (6) asymmetric ene-type reaction, (7) asymmetric cycloaddition reaction, (8) asymmetric ring-opening reaction, and (9) asymmetric miscellaneous reaction.
引用
收藏
页码：147 / 191
页数：45
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