Oxidative Catalysis Using the Stoichiometric Oxidant as a Reagent: An Efficient Strategy for Single-Electron-Transfer-Induced Tandem Anion-Radical Reactions

被引：40

作者：

Kafka, Frantisek ^{[1
]}

Holan, Martin ^{[1
]}

Hidasova, Denisa ^{[1
]}

Pohl, Radek ^{[1
]}

Cisarova, Ivana ^{[2
]}

Klepetarova, Blanka ^{[1
]}

Jahn, Ullrich ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Organ Chem & Biochem, Prague 16610, Czech Republic

[2] Charles Univ Prague, Dept Inorgan Chem, Fac Sci, Prague 12843, Czech Republic

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 37期

关键词：

cyclization; domino reactions; electron transfer; Michael addition; radical reactions; VISIBLE-LIGHT PHOTOCATALYSIS; PHOTOREDOX CATALYSIS; C-C; TRANSITION; CYCLIZATION; BONDS;

D O I：

10.1002/anie.201403776

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidative single-electron transfer-catalyzed tandem reactions consisting of a conjugate addition and a radical cyclization are reported, which incorporate the mandatory terminal oxidant as a functionality into the product.

引用

页码：9944 / 9948

页数：5