Complexes of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with 4-chloro-2-methoxybenzoic acid anion -: Physico-chemical properties

The complexes of 4-chloro-2-methoxybenzoic acid anion with Mn2+, Co2+, Ni2+, Cu2+ and Zn2+ were obtained as polycrystalline solids with general formula M(C8H6ClO3)(2)center dot nH(2)O and colours typical for M(II) ions (Mn - slightly pink, Co - pink, Ni - slightly green, Cu - turquoise and Zn - white). The results of elemental, thermal and spectral analyses suggest that compounds of Mn(II), Cu(II) and Zn(II) are tetrahydrates whereas those of Co(II) and Ni(II) are pentahydrates. The carboxylate groups in these complexes are monodentate. The hydrates of 4-chloro-2-methoxybenzoates of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) heated in air to 1273 K are dehydrated in one step in the range of 323-411 K and form anhydrous salts which next in the range of 433-1212 K are decomposed to the following oxides: Mn3O4, CoO, NiO and ZnO. The final products of decomposition of Cu(II) complex are CuO and Cu. The solubility value in water at 293 K for all complexes is in the order of 10(-3) mol dm(-3). The plots of chi(M) vs. temperature of 4-chloro-2-methoxybenzoates of Mn(II), Co(II), Ni(II) and Cu(II) follow the Curie-Weiss law. The magnetic moment values of Mn2+, Co2+, Ni2+ and Cu2+ ions in these complexes were determined in the range of 76-303 K and they change from: 5.88-6.04 mu(B) for Mn(C8H6ClO3)(2)center dot 4H(2)O, 3.96-4.75 mu(B) for Co(C8H6ClO3)(2)center dot 5H(2)O, 2.32-3.02 mu(B) for Ni(C8H6ClO3)(2)center dot 5H(2)O and 1.77-1.94 mu(B) for Cu(C8H6ClO3)(2)center dot 4H(2)O.