Recent Progress in Transition Metal-Catalyzed Coupling Reactions of Organotitanium Reagents

被引：1
|
作者：
Huang, Hui [1 ]
Li, Juanhua [1 ]
Liu, Kunming [1 ]
Liu, Jinbiao [1 ]
机构：
[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 39卷 / 05期
基金：
中国国家自然科学基金;
关键词：
transition metal; catalysis; organotitanium reagent; coupling; HIGHLY DIASTEREOSELECTIVE ADDITION; LOW-VALENT TITANIUM; GRIGNARD-REAGENTS; ARYL HALIDES; ENANTIOSELECTIVE ADDITION; BIARYL COUPLINGS; ROOM-TEMPERATURE; BENZOIC-ACIDS; LK-ADDITION; COMPLEXES;
D O I：
10.6023/cjoc201810036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Organotitanium proves to be one of ideal organometallic candidates because of its low price, non-toxicity, diversified types, excellent chemo-, regio- and stereo-selectivities. The reactivity of organotitanium reagent could be easily controlled by ligands of central titanium atom. Recently, the coupling reactions of organotitanium reagent have attracted extensive attention. This review summerized recent progress in transiton metal-catalyzed coupling reactons of organotitanium reagents concerning their types.
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页码：1293 / 1303
页数：11
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