Design and synthesis of a new fluorescent tripod for chemosensor applications

被引:8
|
作者
Makki, Mohammad S. I. [1 ]
Staneva, Desislava [2 ]
Sobahi, Tariq R. [1 ]
Bosch, Paula [3 ]
Abdel-Rahman, Reda M. [1 ]
Grabchev, Ivo [1 ,4 ]
机构
[1] King Abdulaziz Univ, Dept Chem, Fac Sci, Jeddah 21589, Saudi Arabia
[2] Univ Chem Technol & Met, BU-1756 Sofia, Bulgaria
[3] CSIC, Inst Sci & Technol Polymers, E-28006 Madrid, Spain
[4] Sofia Univ St Kliment Ohridski, Fac Med, Sofia 1407, Bulgaria
关键词
Tripod; 1,8-Naphthalimide; Sensor; Metalions; pH; PHOTOINDUCED ELECTRON-TRANSFER; TRANSITION-METAL IONS; COLORIMETRIC CHEMOSENSORS; LUMINESCENT SENSORS; CATIONS; 1,8-NAPHTHALIMIDE; DENDRIMERS; PROTONS; SYSTEMS; ENHANCEMENT;
D O I
10.1016/j.tet.2014.10.041
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new yellow-green fluorescent tripod based 1,8-naphthalimide has been synthesized and characterised. Its photophysical properties have been investigated in organic solvents of different polarity. The effect that the metal ions (Cd2+, Co2+, Zn2+, Mn2+, Mg2+, Ni2+, Pb2+, Cu2+, Ba2+, Fe3+ and Ag) produce upon the fluorescent intensity of acetonitrile solutions of the tripod has been discussed viewing its potential applications as a detector for metal cations. The influence of protons on the fluorescence intensity of the tripod in DMF and methanol-water (1:4 v/v) solutions has also been investigated. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:9366 / 9372
页数:7
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