Synthesis and upconversion luminescent properties of BaMgF4 : Er3+, Yb3+ nanocrystals

被引:3
|
作者
Pan Cheng-Long [1 ]
Liu Hong-Li [1 ]
Guo Yun [1 ]
Jing Shu [1 ]
Sun Jing [1 ]
Zhou He-Feng [1 ]
Wang Hua [1 ]
机构
[1] Taiyuan Univ Technol, Key Lab Interface Sci & Engn, Minist Educ, Taiyuan 030024, Peoples R China
基金
中国国家自然科学基金;
关键词
BaMgF4; Er3+; Yb3+; reverse co-precipitation; upconversion; PHASE; SIZE;
D O I
10.7498/aps.63.154211
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
BaMgF4 : Er3+, Yb3+ nanocrystals in rod-shape are synthesized by means of the reverse co-precipitation. They emit green and red light under excitation of near-infrared light (980 nm). The green and red emissions may be attributed to the H-2(11/2)-I-4(15/2), S-4(3/2)-I-4(15/2) and F-4(9/2)-I-4(15/2) transitions of Er3+. Dopant ions Yb3+ as sensibilizers can improve the upconversion transformation efficiency. The emission intensity is the strongest when the contents of Er3+ and Yb3+ are 3% and 10%, respectively. With increasing concentration of Yb3+, the red emission intensity increases while the green emission reduces. And the conversion fitting curve between the luminous intensity and pump current indicates that the upconversion process of the green and red light of BaMgF4 : Er3+, Yb3+ is due to two-photon absorption.
引用
收藏
页数:5
相关论文
共 18 条
  • [1] Upconversion and anti-stokes processes with f and d ions in solids
    Auzel, F
    [J]. CHEMICAL REVIEWS, 2004, 104 (01) : 139 - 173
  • [2] Direct upconversion sensitization luminescence of Er:oxyfluoride glassceramics
    Chen, XB
    Li, MX
    Sawanobori, N
    Zhe, Z
    Nie, YX
    [J]. ACTA PHYSICA SINICA, 2000, 49 (12) : 2482 - 2487
  • [3] Chen XB, 2003, CHINESE PHYS, V12, P1451, DOI 10.1088/1009-1963/12/12/020
  • [4] Influences of Mg2+ ion on dopant occupancy and upconversion luminescence of Ho3+ ion in LiNbO3 crystal
    Dai Li
    Xu Chao
    Zhang Ying
    Li Da-Yong
    Xu Yu-Heng
    [J]. CHINESE PHYSICS B, 2013, 22 (09)
  • [5] Efficient white light emission by upconversion in Yb3+-, Er3+- and Tm3+-doped Y2BaZnO5
    Etchart, Isabelle
    Berard, Mathieu
    Laroche, Marine
    Huignard, Arnaud
    Hernandez, Ignacio
    Gillin, William P.
    Curry, Richard J.
    Cheetham, Anthony K.
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (22) : 6263 - 6265
  • [6] Optical spectroscopy of Yb3+ centers in BaMgF4 ferroelectric crystal
    Garcia-Santizo, J. V.
    del Rosal, B.
    Ramirez, M. O.
    Bausa, L. E.
    Villora, E. G.
    Molina, P.
    Vasyliev, V.
    Shimamura, K.
    [J]. JOURNAL OF APPLIED PHYSICS, 2011, 110 (06)
  • [7] Haiyan D, 2010, J RARE EARTH, V28, P697
  • [8] Highly efficient multicolour upconversion emission in transparent colloids of lanthanide-doped NaYF4 nanocrystals
    Heer, S
    Kömpe, K
    Güdel, HU
    Haase, M
    [J]. ADVANCED MATERIALS, 2004, 16 (23-24) : 2102 - +
  • [9] Ho Enjie, 2012, CHINESE PHYS B, V21, P241
  • [10] Li Tanggang, 2011, ACTA PHYS SINICA, V60, P230