Synthesis of some new enantiopure [2.2]paracyclophanes bearing polycyclic aromatic subunits

被引：0
|
作者：
Taticchi, A
Minuti, L
Marrocchi, A
Lanari, D
Gacs-Baitz, E
机构：
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
[2] Hungarian Acad Sci, Cent Inst Chem, H-1525 Budapest, Hungary
来源：
TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 12期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of some new optically active[2.2]paracyclophanes containing condensed polycyclic aromatic subunits is described. The Diels-Alder reactions of (S)-(+)-4-ethenyl[2.2]paracyclophane with 1,4-naphthoquinone, 5-hydroxy-1,4-naphthoquinone and 5,8-dihydroxy-1,4-naphthoquinone have been studied. The effect of the hydroxy group(s) on the reactivity of the dienophiles and on the regioselectivity of the Diels-Alder reaction has been discussed. A structural analysis of the reaction products by H-1 and C-13 NMR spectroscopy is also presented. (C) 2002 Elsevier Science Ltd. All rights reserved.
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页码：1331 / 1335
页数：5
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