A Comparative Study of the Catalytic Activity of Sulfonic Acid Cation-Exchange Resins with a Macroporous and Gel Structure in Fatty Acid Esterification

被引：0
|
作者：
Otopkova, K. V. [1 ,2 ]
Esipovich, A. L. [1 ,2 ]
Kanakov, E. A. [1 ]
Charykova, T. A. [1 ]
Baydachenko, V. E. [1 ]
Ryabova, T. A. [1 ]
机构：
[1] Nizhnii Novgorod State Tech Univ, Nizhnii Novgorod 603950, Russia
[2] Lobachevsky State Univ Nizhny Novgorod, Natl Res Univ, Nizhnii Novgorod 603022, Russia
来源：
KINETICS AND CATALYSIS | 2022年 / 63卷 / 06期
关键词：
cation-exchange resins; sulfonic acid cation-exchange resins; fatty acid methyl esters; fatty acids; esterification; BIODIESEL PRODUCTION; OLEIC-ACID; TRANSESTERIFICATION; PERFORMANCE; WASTE; OILS; PLASTICIZER;
D O I：
10.1134/S002315842206009X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The activity and stability of cation-exchange resins in fatty acid esterification with methyl alcohol have been studied. The cation-exchange resins have been characterized by IR spectroscopy, electron microscopy, and low-temperature nitrogen adsorption-desorption (BET method). It has been shown that, due to a developed surface and a larger pore volume, the reaction products are readily desorbed and thereby prevent the catalytic sites from blocking and the catalyst from losing activity. Of the studied cation-exchange resins, the best results have been obtained in the case of using the Lewatit MonoPlus SP 112 cation-exchange resin with a macroporous structure.
引用
收藏
页码：666 / 675
页数：10
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