Two triple points in the H2O-H2 system

被引:6
|
作者
Efimchenko, V. S. [1 ]
Antonov, V. E. [1 ]
Barkalov, O. I. [1 ]
Klyamkin, S. N. [2 ]
Tkacz, M. [3 ]
机构
[1] Russian Acad Sci, Inst Solid State Phys, Moscow 142432, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[3] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
基金
俄罗斯基础研究基金会;
关键词
hydrogen hydrates; high pressures; phase equilibria; 1.8; KBAR; HYDROGEN; PRESSURES;
D O I
10.1080/08957950902734013
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Using a volumetric technique, phase transitions in the H2O-H2 system were investigated in the vicinity of two points of an invariant equilibrium, L+Ih+sII and L+sII+C1, located at 1.07kbar and-10C and at 3.6kbar and 1C, respectively. Liquid water (L), low-pressure hexagonal ice (Ih) and high-pressure cubic (sII) and rhombohedral (C1) clathrate hydrates were in equilibrium with gaseous hydrogen taken in excess.
引用
收藏
页码:250 / 253
页数:4
相关论文
共 50 条
  • [1] Potential Energy Surface for the H2O-H2 System
    Barreto, P. R. P.
    Ribas, V. W.
    Palazzetti, F.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (52): : 15047 - 15054
  • [2] DECARBURIZATION OF TRANSFORMER STEEL IN H2O-H2 MIXTURES
    ROGOV, AI
    TOMILIN, IA
    SHVARTSMAN, LA
    RUSSIAN METALLURGY, 1975, (03): : 152 - 157
  • [3] Theoretical study of the rovibrational spectrum of H2O-H2
    Wang, Xiao-Gang
    Carrington, Tucker, Jr.
    JOURNAL OF CHEMICAL PHYSICS, 2011, 134 (04):
  • [4] TRENDS IN THE TECHNOLOGY OF THE H2O-H2 ISOTOPIC EXCHANGE
    PECULEA, M
    REVUE ROUMAINE DE PHYSIQUE, 1988, 33 (4-6): : 797 - 801
  • [5] CONTROLLED REDUCTION OF COPPER TUNGSTATE IN H2O-H2 MIXTURES
    BASU, AK
    SALE, FR
    JOURNAL OF MATERIALS SCIENCE, 1979, 14 (01) : 91 - 99
  • [6] 高温H2O-H2系统透平设计
    尉良川
    李南宜
    李梦馨
    郭冰
    青海大学学报, 2023, 41 (01) : 8 - 14
  • [7] Study on liquid catalytic isotopic exchange of H2O-H2
    Ruan, Hao
    Hu, Shi-Lin
    Zhang, Li
    Hu, Zhen-Zhong
    Dou, Qin-Cheng
    Yuanzineng Kexue Jishu/Atomic Energy Science and Technology, 2005, 39 (04): : 318 - 321
  • [8] 氧对H2O-H2及H2O-H2惰气混合气体氧位的影响
    方正
    陈新民
    金属学报, 1989, (04) : 81 - 88
  • [9] GASIFICATION OF A GERMAN BITUMINOUS COAL WITH H2O H-2 AND H2O-H2 MIXTURES
    FEISTEL, PP
    VANHEEK, KH
    JUNTGEN, H
    PULSIFER, AH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 173 (MAR20): : 7 - 7
  • [10] Formation and composition of the clathrate phase in the H2O-H2 system at pressures to 1.8 kbar
    O. I. Barkalov
    S. N. Klyamkin
    V. S. Efimchenko
    V. E. Antonov
    Journal of Experimental and Theoretical Physics Letters, 2005, 82 : 413 - 415