The control of nonstoichiometry in lithium nickel-cobalt oxides

被引:26
|
作者
Gover, RKB
Yonemura, M
Hirano, A
Kanno, R
Kawamoto, Y
Murphy, C
Mitchell, BJ
Richardson, JW
机构
[1] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan
[2] Argonne Natl Lab, Intense Pulsed Neutron Source, Argonne, IL 60439 USA
关键词
LiNiO2; layered materials; cation disorder; rietveld analysis; neutron diffraction; reversibility;
D O I
10.1016/S0378-7753(99)00100-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The nonstoichiometry of layered Li1-x(Ni0.8Co0.2)(1+x)O-2 has been controlled by varying the starting composition and preparation temperature. X-ray and neutron powder diffraction has been used to determine the composition of the materials prepared, and the electrochemical properties have been examined. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:535 / 541
页数:7
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