Electrochemical reduction of the anion of 1-isoquinolinecarboxylic acid:: an unexpected reaction of cathodic decarboxylation

被引：5
|
作者：
Sànchez-Sànchez, CM
Expósito, E
Batanero, R
Montiel, V
Barba, F
Aldaz, A
机构：
[1] Univ Alicante, Dept Quim Fis, Inst Electroquim, E-03080 Alicante, Spain
[2] Univ Alcala de Henares, Dept Quim Organ, E-28871 Alcala De Henares, Spain
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2004年 / 6卷 / 06期
关键词：
1-isoquinolinecarboxylic acid; isoquinaldic acid; isoquinoline; decarboxylation; electrochemical reduction;
D O I：
10.1016/j.elecom.2004.04.012
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical reduction of the anion of 1-isoquinolinecarboxylic acid yields isoquinoline. This is an unexpected and surprising result because, until we know, a cathodic decarboxylation of a monocarboxylic acid has never been reported. A plausible reaction route for the cathodic reduction is proposed. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：595 / 599
页数：5
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