Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond

被引：450
|
作者：
Resa, I
Carmona, E
Gutierrez-Puebla, E
Monge, A
机构：
[1] Univ Sevilla, CSIC, Dept Quim Inorgan, Inst Invest Quim, Seville 41092, Spain
[2] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain
来源：
SCIENCE | 2004年 / 305卷 / 5687期
关键词：
D O I：
10.1126/science.1101356
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Unlike mercury, which has an extensive +1 oxidation state chemistry, zinc usually adopts the +2 oxidation state. Decamethyldizincocene, Zn-2(eta(5)-C5Me5)(2), an organometallic compound of Zn(I) formally derived from the dimetallic [Zn-Zn](2+) unit, has been isolated from the low-temperature (-10degreesC) reaction of Zn(C5Me5)(2) and Zn(C,H,), in diethyl ether. X-ray studies show that it contains two eclipsed Zn(eta(5)-C5Me5) fragments with a Zn-Zn distance (+/- standard deviation) of 2.305(+/-3) angstroms, indicative of a metal-metal bonding interaction.
引用
收藏
页码：1136 / 1138
页数：3
相关论文
共 50 条
  • [1] Theoretical analysis of the vibrational modes in decamethyldizincocene (Zn2(η5-Cp*)2):: A stable organometallic compound of Zn(I) with a Zn-Zn bond.
    Richardson, SL
    Baruah, T
    Pederson, MR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1099 - U1099
  • [2] Decamethyidizincocene, a stable compound of Zn(I) with a Zn-Zn bond (vol 305, pg 1136, 2004)
    Resa, I
    SCIENCE, 2004, 306 (5695) : 411 - 411
  • [3] Searching for the vibrational signatures of the Zn-Zn stretching mode in decamethyldizincocene (Zn2(η5-Cp*)2):: The first organometallic compound with a metallic homonuclear Zn-Zn bond
    Richardson, SL
    Baruah, T
    Pederson, MR
    CHEMICAL PHYSICS LETTERS, 2005, 415 (1-3) : 141 - 145
  • [4] The Reaction of Dizincocene with Preservation of the Zn-Zn Bond
    Schuchmann, Daniella
    Westphal, Ulrich
    Schulz, Stephan
    Floerke, Ulrich
    Blaeser, Dieter
    Boese, Roland
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (04) : 807 - 810
  • [5] A theoretical investigation of Zn-Zn and Be-Be one electron bond
    Sarmah, Kangkan
    Kalita, Amlan J.
    Guha, Ankur K.
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2023, 123 (01)
  • [6] Synthesis and Reactivity of Triangular Heterometallic Complexes Containing Zn-Zn Bond
    Jiang, Shengjie
    Cai, Yanping
    Carpentier, Ambre
    del Rosal, Iker
    Maron, Laurent
    Xu, Xin
    INORGANIC CHEMISTRY, 2022, 61 (20) : 8083 - 8089
  • [7] INTERFACE TENSIONS IN ZN-ZN, ZN-SN AND ZN-SN-PB SYSTEMS
    EUSTATHOPOULOS, N
    PASSERONE, A
    CHIMICA & L INDUSTRIA, 1977, 59 (04): : 301 - 301
  • [8] Could we make shorter Zn-Zn bonds?
    Alvarez, Santiago
    Echeverria, Jorge
    Falceto, Andres
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [9] Experimental and theoretical characterization of the Zn-Zn bond in [Zn2(η5-C5Me5)2]
    Van der Maelen, Juan F.
    Gutierrez-Puebla, Enrique
    Monge, Angeles
    Garcia-Granda, Santiago
    Resa, Irene
    Carmona, Ernesto
    Fernandez-Diaz, Maria Teresa
    Mclntyre, Garry J.
    Pattison, Philip
    Weber, Hans-Peter
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2007, 63 : 862 - 868
  • [10] Subvalent compounds featuring direct metal-metal bonds:: The Zn-Zn bond in [Cp*2Zn2]
    Schnepf, A
    Himmel, HJ
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (20) : 3006 - 3008
12345