Tris(2,2′-bipyridyl-N,N′)nickel(II) thiosulfate heptahydrate

被引:0
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作者
Freire, E
Baggio, S
Mombru, A
Baggio, R [1 ]
机构
[1] Univ Nacl Patagonia, Sede Puerto Madryn, RA-9120 Puerto Madryn, Chubut, Argentina
[2] CenPat, Puerto Madryn, Chubut, Argentina
[3] CONICET, RA-1033 Buenos Aires, DF, Argentina
[4] Univ Republ, Fac Quim, CSSC Lab, Montevideo, Uruguay
[5] Comis Nacl Energia Atom, Dept Fis, Buenos Aires, DF, Argentina
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of the title compound, [Ni(C10H8N2)(3)](S2O3). 7H(2)O, consists of monomeric Ni(bipy)(3)(2+) cations embedded in an anionic network made up of S2O32- ions and hydration water molecules. The structure presents the unusual feature of two neighbouring thiosulfates approaching linearly head-to-head with an unusually short S ... S contact distance of 3.25 Angstrom.
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页码:541 / 543
页数:3
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