Highly chemo- and regio-selective [2+2+2] cycloaddition of unsymmetrical 1,6-diynes with terminal alkynes catalyzed by Cp*Ru(cod)Cl under mild conditions

被引：106
|
作者：
Yamamoto, Y [1 ]
Ogawa, R [1 ]
Itoh, K [1 ]
机构：
[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/b000466i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ru(II)-catalyzed cycloaddition of unsymmetrical 1,6-diynes gives the desired cycloadducts in high yields with a regioselectivity meta : ortho = 88 : 12-98 : 2.
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收藏
页码：549 / 550
页数：2
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