Organometallic water splitting - from coordination chemistry to catalysis

被引：10

作者：

Klahn, Marcus ^{[1
]}

Beweries, Torsten ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

REVIEWS IN INORGANIC CHEMISTRY | 2014年 / 34卷 / 03期

关键词：

homogeneous catalysis; hydrogen; organometallic chemistry; water splitting; FACILE OXIDATIVE ADDITION; HYDROGEN GENERATION; DIORGANOPALLADIUM(II) COMPLEXES; HOMOGENEOUS CATALYSTS; PHOSPHINE COMPLEXES; IRIDIUM COMPLEXES; RUTHENIUM COMPLEX; DONOR-LIGAND; O-H; REDUCTION;

D O I：

10.1515/revic-2013-0019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review gives an overview on the recent developments in the field of coordination chemistry of water at transition metal centres, which could give implications for a better understanding of the elementary steps of light-driven overall water splitting. Additionally, selected examples for homogeneous catalyst systems that are capable of producing hydrogen and/or oxygen from water are presented, focussing on the mechanistic aspects of water reduction and water oxidation.

引用

页码：177 / 198

页数：22

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