Synthesis and structure of chiral (R)-2,2′-bis-silyl-substituted 1,1′-binaphthyl derivatives

被引：18
|
作者：
Hoshi, T
Shionoiri, H
Suzuki, T
Ando, M
Hagiwara, H
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan
[2] Niigata Univ, Fac Engn, Niigata 9502181, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 11期
关键词：
D O I：
10.1246/cl.1999.1245
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
First synthesis of optically active 2,2'-bis-silyl-substituted 1,1'-binaphthyl derivatives, (R)-(+)-2,2'-bis(trimethylsilyl)-1,1'-binaphthyl ((R)-(+)-1) and (R)-(-)-2,2'-bis(dimethylphenylsilyl)-1,1'-binaphthyl ((R)-(-)-2), has been accomplished by the direct bis-silylation of chiral 2,2'-dibromo-1,1'-binaphthyl (DBBN). The molecular structure and the absolute configuration of (R)-(-)2 have been determined by means of X-ray crystallography.
引用
收藏
页码：1245 / 1246
页数：2
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