2,4-[2,2'-Methylenebis(4-nitrophenoxy)]-2,4,6,6-tetrachlorocyclo-2λ5,4λ5,6λ5-triphosphazatriene (ansa)

被引：11
|
作者：
Hökelek, T
Akduran, N
Yildiz, M
Dal, H
Kiliç, Z
机构：
[1] Univ Hacettepe, Dept Phys, TR-06532 Ankara, Turkey
[2] Ankara Univ, Dept Chem, TR-06100 Ankara, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷 / 01期
关键词：
D O I：
10.1107/S0108270199012986
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, C13H8C14N5O6P3, consists Of a non-planar trimeric phosphazene ring and a bulky 2,2'-methylenebis(4-nitrophenoxy) side group which predominantly determines the molecular shape. With respect to the corresponding values in the reference compound N3P3Cl6, the endocyclic angle around one P atom is the same, but the exocyclic angle is increased, while the endocyclic and exocyclic angles about another P atom are both decreased. This situation is different from that in other reported phosphazene derivatives.
引用
收藏
页码：90 / 92
页数：3
相关论文
共 50 条
  • [1] cis-ansa-2,4-Dichloro-2,4-[2,2′-methylenebis(4-nitrophenoxy)]-6,6-diphenylcyclo-2λ5,4λ5,6λ5-triphosphazatriene
    Hökelek, T
    Dal, H
    Kiliç, Z
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O1063 - O1066
  • [2] Synthesis and characterization of phenoxyphosphazenes.: Structure of 2,2-[2,2′-metheylenebis(4-chlorophenoxy)]-4,4,6,6-tetrachlorocyclo-2λ5,4λ5,6λ5-triphosphazatriene (spiro)
    Yildiz, M
    Erdener, D
    Ünver, H
    Iskeleli, NO
    JOURNAL OF MOLECULAR STRUCTURE, 2005, 753 (1-3) : 165 - 172
  • [3] 2,2-[2,2′-Methylenebis(4-nitrophenoxy)]-4,6-[2,2′-methylenebis(4-nitrophenoxy)]-4,6-dichloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphorine (spiro-ansa) acetonitrile
    Öztürk, L
    Hökelek, T
    Dal, H
    Kiliç, Z
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : O20 - O23
  • [4] Crystal Structure of 2,4,4,6,6-Pentachloro-2-(2,4,6-trimethylphenoxy)cyclo-2λ5,4λ5,6λ5-triphosphazatriene
    Tuncer HökeleK
    Nurcan Akduran
    Adem Kiliç
    Saliha Begeç
    Zeynel Kiliç
    Analytical Sciences, 2000, 16 : 101 - 102
  • [5] Crystal structure of 2,4,4,6,6-pentachloro-2-(2,4,6-trimethylphenoxy)cyclo-2λ5,4λ5,6λ5-triphosphazatriene
    Hökelek, T
    Akduran, N
    Kiliç, A
    Begeç, S
    Kiliç, Z
    ANALYTICAL SCIENCES, 2000, 16 (01) : 101 - 102
  • [6] 2,4,4,6,6-Pentachloro-2-(2,6-di-tert-butyl-4-methylphenoxy)cyclo-2λ5,4λ5,6λ5-triphosphazatriene
    Hökelek, T
    Kiliç, A
    Begeç, S
    Kiliç, Z
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 783 - 785
  • [7] Phosphorus-nitrogen compounds:: Part IV.: New podand and lariat ether-type macrocycles with cyclophosphazenes.: Structure of 2,2′-[triethyleneglycolbis(phenylether-2-amino)]-2,2′,4,4,4′,4′,6,6,6′,6′-decachlorobicyclo-2λ5, 2′λ5, 4λ5, 4′λ5, 6λ5, 6′λ5-triphosphazatriene
    Yildiz, M
    Kiliç, Z
    Hökelek, T
    JOURNAL OF MOLECULAR STRUCTURE, 1999, 510 (1-3) : 227 - 235
  • [8] 2-[(2,4,4,6,6-Pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinin-2-yl)azanidyl]pyridinium
    Ahmed, Safaa A.
    Haque, Rosenani A.
    Zetty, Zulikha H.
    Fun, Hoong-Kun
    Loh, Wan-Sin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O306 - U1873
  • [9] 4,4,6,6-tetrachloro-2-[(2,4-dimethylphenyl)sulfanyl]-N-[4-(2,2,4,4-tetrachloro-1,3,5,7,11-pentaaza-2λ5,4λ5,6λ5-triphosphaspiro[5.5] undeca-1,3,5-trien7-yl)butyl]-1,3,5,2λ5,4λ5,6λ5-triaza-triphosphinin-2-amine
    Coles, Simon J.
    Davies, David B.
    Hursthouse, Michael B.
    Ibisoglu, Hanife
    Kilic, Adem
    Shaw, Robert A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3753 - U2529
  • [10] 4,4,6,6-tetrachloro-2,2-(propylenedioxydi-o-phenylenediimino)-2λ5,4λ5,6λ5-cyclotriphosphazene
    Tercan, B
    Hökelek, T
    Bilge, S
    Özgüç, Z
    Kiliç, Z
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : O381 - O383
12345