Characteristics and kinetics of coal char steam gasification under microwave heating

被引:28
|
作者
Liu, Quanrun [1 ]
He, He [1 ]
Li, Haipeng [1 ]
Jia, Jianbo [1 ]
Huang, Guangxu [1 ]
Xing, Baolin [1 ]
Zhang, Chuanxiang [1 ,2 ]
Cao, Yijun [2 ]
机构
[1] Henan Polytech Univ, Coll Chem & Chem Engn, Henan Key Lab Coal Green Convers, Jiaozuo 454003, Henan, Peoples R China
[2] Zhengzhou Univ, Henan Prov Ind Technol Res Inst Resources & Mat, Zhengzhou 450001, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Steam gasification; Microwave heating; Coal char; Kinetics; ASSISTED PYROLYSIS; BIOMASS; CO2; REACTIVITY; SYNGAS; SHELL;
D O I
10.1016/j.fuel.2019.115899
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The behavior and kinetics of coal char steam gasification under microwave heating are investigated. The influence of the coal char particle size, water injection rate, and reaction temperature on the carbon conversion rate and gas product evolution during microwave heating gasification are considered and compared to the results from coal char steam gasification using conventional heating under the same conditions. The results show that microwave heating can accelerate the reaction rate of coal char steam gasification and improve the quality of the gas product. It was found that at temperatures varying from 600 to 900 degrees C, the coal char steam gasification reaction was well described using the shrinking core model (SCM). Activation energies of 82.8 kJ/mol and 114.3 kJ/mol were obtained for microwave heating and conventional electric heating, respectively.
引用
收藏
页数:7
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