Complex formation equilibria of FeIII with boric acid in presence of some aminopolycarboxylic acids

被引：0

作者：

Mukherjee, GN ^{[1
]}

Das, A ^{[1
]}

Bandyopadhyay, S ^{[1
]}

机构：

[1] Univ Calcutta, Univ Coll Sci, Dept Chem, Kolkata 700009, W Bengal, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2004年 / 81卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Equilibrium study on the mixed ligand complex formation of Fe-III with nitrilotriacetic acid and anthranilic acid diacetic acid (H3L) in the absence and in the presence of boric acid in different molar ratios provide the evidence of formation of Fe(L) Fe(OH)(-), Fe(L)(OH)(2)(2-), Fe(L)(H2BO4)(3-) and Fe-2(L)(2)(BO4)(5-) complexes in solution. Stability constants of the complexes and the complex formation equilibria in aqueous solution at 25 +/- 1degrees at a fixed ionic strength, I = 0.1 M (NaNO3) have been determined by potentiometric method.

引用

页码：282 / 286

页数：5