Activated biomass carbon made from bamboo as electrode material for supercapacitors

被引:224
|
作者
Zhang, Guoxiong [1 ]
Chen, Yuemei [1 ]
Chen, Yigang [1 ]
Guo, Haibo [1 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Dept Elect Informat Mat, Shanghai 200444, Peoples R China
关键词
Bamboo; Activation temperature; Supercapacitor; Energy storage; HIGH-PERFORMANCE SUPERCAPACITORS; ELECTROCHEMICAL CAPACITORS; RAMAN-SPECTROSCOPY; OXIDE;
D O I
10.1016/j.materresbull.2018.03.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Activated biomass carbons (ABC) produced from bamboo by carbonization and activation have high specific surface areas and mesoporous structures. The specific surface area, total pore volume, and average pore size of the activated biomass carbon are controlled by adjusting the activation temperature from 700 to 1000 degrees C. The carbon materials activated at 900 degrees C have an optimal mesoporous structure with a high specific surface area (2221.1 m(2) g(-1)), the highest capacitance (293 F g(-1) at 0.5 A g(-1) in 3 M KOH aqueous electrolyte) and excellent rate capability (193.8 F g(-1) at 20 A g(-1)). Symmetric supercapacitors made of the optimal electrodes exhibit a high energy density of 10.9 Wh kg(-1) (18.2 Wh L-1 ) at a power density of 63 W kg(-1) (105 W L-1 ) and outstanding capacitance retention of 91.8% over 10,000 cycles. The high electrochemical performance of the mesoporous ABCs show that they are highly promising for energy-storage applications with further optimization.
引用
收藏
页码:391 / 398
页数:8
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