Transition-metal-catalyzed methods for synthesis of fluorenes

被引：17

作者：

Kaiser, Reinhard P. ^{[1
]}

Caivano, Ilaria ^{[1
]}

Kotora, Martin ^{[1
]}

机构：

[1] Charles Univ Prague, Fac Sci, Dept Organ Chem, Hlavova 8, Prague 12343 2, Czech Republic

来源：

TETRAHEDRON | 2019年 / 75卷 / 22期

关键词：

Fluorenes; Catalysis; Synthesis; Transition metal complexes; C-H ACTIVATION; PD(OAC)(2)-CATALYZED DOMINO REACTIONS; INTRAMOLECULAR ACYLATION; SUBSTITUTED FLUORENES; EFFICIENT SYNTHESIS; BENZOIC ANHYDRIDES; GRIGNARD-REAGENTS; BOND ACTIVATION; DERIVATIVES; FLUOREN-9-ONES;

D O I：

10.1016/j.tet.2019.04.045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This report aims to summarize recent advances in syntheses of fluorenes and derivatives thereof by using methods based on catalytic or stoichiometric transformations of various aromatic compounds induced by transition metal compounds. These methods encompass various inter- and intramolecular processes such as cross-coupling reactions, carbonylations, C-H activations, electrophilic aromatic substitutions, cycloaddition reactions of alkenes and alkynes. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：2981 / 2992

页数：12

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