Synthesis of 1-Naphthol-based Unsymmetrical Triarylmethanes: Heck-type Desulfitative Reaction of Arylsulfonyl Chlorides with Tetralone-derived Chalcones

被引：2

作者：

Sankar, Rathinam ^{[1
]}

Bhattacharya, Debabrata ^{[1
]}

Arulananda Babu, Srinivasarao ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res IISER Mohali Knowledge, Dept Chem Sci, Sect 81,Manauli PO, Mohali 140306, Punjab, India

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 10卷 / 03期

关键词：

Heck reaction; 1-naphthol compounds; palladium; unsymmetrical triarylmethane; synthetic methods; FRIEDEL-CRAFTS ALKYLATION; ORTHO-QUINONE METHIDES; ARYL SULFINIC ACIDS; C-H BONDS; ENANTIOSELECTIVE SYNTHESIS; CONVENIENT SYNTHESIS; CONJUGATE ADDITION; 2-NAPHTHOL DERIVATIVES; CATALYZED ARYLATION; CROSS-COUPLINGS;

D O I：

10.1002/ajoc.202100016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the preliminary results of an investigation comprising of the synthesis of 1-naphthol-based unsymmetrical triarylmethanes via the Pd-catalyzed Heck-type desulfitative reaction and conjugate addition of arylsulfonyl chlorides with tetralone-derived chalcones. Unsymmetrical triarylmethanes are valuable molecules in organic-, medicinal and materials chemistry. This work is a contribution towards enriching the library of unsymmetrical triarylmethanes.

引用

页码：576 / 581

页数：6