Microwave dielectric properties of a (La,Nd)4Ti4O15 (A=Ca, Sr) ceramics with hexagonal perovskite structure
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Yue, ZX
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Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R ChinaTsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
Yue, ZX
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Zhao, F
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Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R ChinaTsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
Zhao, F
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Zhang, YC
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Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R ChinaTsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
Zhang, YC
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Gui, ZL
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Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R ChinaTsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
Gui, ZL
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Li, LT
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Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R ChinaTsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
Li, LT
[1
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机构:
[1] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
The influences of Nd substitution for La in A (La1-xNdx)(4)Ti4O15 (A=Ca, Sr) (x=0-0.5) microwave ceramics on phases and dielectric properties were investigated. It showed that Nd substitution for La has remarkable effect on the phase compositions. As x less than or equal to 0.125, the sintered ceramics remains a single hexagonal perovskite phase. When x increases to 0.25 and 0.50, the hexagonal perovskite becomes unstable and the secondary phases of Ca(La1-xNdx)(4)Ti5O17 and Sr(La,Nd)(2)Ti2O8 with orthorhombic perovskite structures are formed. The lattice parameters of hexagonal perovskite cell decrease linearly with the increasing of Nd content. The Nd substitution for La can improve the temperature stability of ceramics, but decrease the dielectric constants and Qxf values to some extent.