Studies of the molybdenum migration from Ni/Mo catalysts in the presence of steam

被引：2

作者：

Grzegorczyk, W ^{[1
]}

Denis, A ^{[1
]}

Borowiecki, T ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Chem Technol, PL-20031 Lublin, Poland

来源：

CATALYSIS COMMUNICATIONS | 2002年 / 3卷 / 07期

关键词：

D O I：

10.1016/S1566-7367(02)00131-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The extent of molybdenum loss was examined as a function of the initial Mo concentration in the Ni-Mo steam reforming catalysts and a partial pressure of water in the reaction mixtures. It was found that molybdenum loss at high temperature (similar to 800 degreesC) is prevented by the presence of even small content of hydrogen in the mixture. The kinetic equation describing the rate of Mo loss from the studied catalysts is presented. The possible application of Ni-Mo catalysts resistant to coking in the hydrocarbon steam reforming is discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：293 / 297

页数：5

共 50 条

[1] Ni catalysts with Mo promoter for methane steam reforming
Maluf, S. S.
Assaf, E. M.
[J]. FUEL, 2009, 88 (09) : 1547 - 1553
[2] STUDIES OF MOLYBDENUM IN MO-TI OXIDE CATALYSTS
KRAVETS, GA
SHOKHIREVA, TK
ANUFRIENKO, VF
YURIEVA, TM
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1982, 19 (1-2): : 95 - 99
[3] Steam gasification of bitumen oil in presence of Ni/dolomite catalysts
Gao, Yun
Ghorbanian, Babak
Gargari, Hossein Najari
Gao, Wei
[J]. PETROLEUM SCIENCE AND TECHNOLOGY, 2017, 35 (21) : 2074 - 2079
[4] CATALYTIC STEAM CRACKING OF VACUUM RESIDUE IN PRESENCE OF DISPERSED CATALYSTS BASED ON MO, NI, FE, CO, AL METALS
Sosnin, Gleb A.
Zaikina, Olesya O.
Eletskii, Petr M.
Yakovlev, Vadim A.
[J]. BULLETIN OF THE TOMSK POLYTECHNIC UNIVERSITY-GEO ASSETS ENGINEERING, 2018, 329 (12): : 145 - 154
[5] MAS NMR, ESR and TPD studies of Mo/HZSM‐5 catalysts: evidence for the migration of molybdenum species into the zeolitic channels
Ding Ma
Weiping Zhang
Yuying Shu
Xiumei Liu
Yide Xu
Xinhe Bao
[J]. Catalysis Letters, 2000, 66 : 155 - 160
[6] Synthesis of Carbon Nanotubes from Polypropylene in the Presence of Ni/Mo/MgO Catalysts via Combustion
Song, Rongjun
Ji, Qing
[J]. CHEMISTRY LETTERS, 2011, 40 (10) : 1110 - 1112
[7] GRAIN-BOUNDARY MIGRATION IN RECRYSTALLIZED MO FOILS IN THE PRESENCE OF NI
HOFMANNAMTENBRINK, M
KAYSSER, WA
PETZOW, G
[J]. JOURNAL DE PHYSIQUE, 1985, 46 (NC-4): : 545 - 552
[8] GRAIN-BOUNDARY MIGRATION IN RECRYSTALLIZED MO FOILS IN THE PRESENCE OF NI
HOFMANNAMTENBRINK, M
KAYSSER, WA
PETZOW, G
[J]. ZEITSCHRIFT FUR METALLKUNDE, 1982, 73 (05): : 305 - 310
[9] MAS NMR, ESR and TPD studies of Mo/HZSM-5 catalysts: evidence for the migration of molybdenum species into the zeolitic channels
Ma, D
Zhang, WP
Shu, YY
Liu, XM
Xu, YD
Bao, XH
[J]. CATALYSIS LETTERS, 2000, 66 (03) : 155 - 160
[10] COMPARATIVE HYDRODENITROGENATION ACTIVITY OF MOLYBDENUM, CO-MO AND NI-MO ALUMINA-SUPPORTED CATALYSTS
LEDOUX, MJ
DJELLOULI, B
[J]. APPLIED CATALYSIS, 1990, 67 (01): : 81 - 92

← 1 2 3 4 5 →