Synthesis of TS-1 Films on Porous Supports for Epoxidation of Allyl Chloride by Hydrogen Peroxide

被引：0

作者：

Gu Ling ^{[1
,2
]}

Wang Li ^{[2
]}

机构：

[1] Shanxi Datong Univ, Sch Chem & Environm Engn, Datong 037009, Peoples R China

[2] Tianjin Univ, Key Lab Green Chem Technol, Minist Educ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China

来源：

CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY | 2013年 / 15卷 / 03期

关键词：

TS-1; film; epoxidation; epichlorohydrin; TITANIUM SILICALITE; MEMBRANES; NORBORNADIENE; ZEOLITE; METAL; ISOMERIZATION; QUADRICYCLANE; TI; OPTIMIZATION; PROPYLENE;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Titanium silicalite-1 (TS-1) films were synthesized on stainless steel plate, glass slide and monolith supports via an in-situ hydrothermal method. Characterization data showed that the formation of TS-1 films was easier on the porous flat support with rough surface such as monolith than on the smooth non-porous supports like glass slide and stainless steel plate. The film on the monolith had the highest uniformity and smallest size of crystals. The catalytic property of monolith-supported film was tested for epoxidation of allyl chloride (ACH) by H2O2 in a fixed bed reactor. Under the condition of a methanol (solvent)/ACH (90%)/H2O2 (30%) ratio of 12:1:1, a LHSV of 1.35 h(-1) and a temperature of 318 K, the conversion of allyl chloride and the selectivity to epichlorohydrin reached 79 % and 51 %, respectively.

引用

页码：45 / 49

页数：5

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