1,1′-Binaphthyl-2,2′-diamine Dihydrochloride: an Efficient Ligand for the N-Arylation of Imidazole with Aryl/heteroaryl Halides Catalyzed by CuI

被引：3

作者：

Shen Guodong ^{[1
]}

Zhao Lingyu ^{[1
]}

Bao Weiliang ^{[2
]}

机构：

[1] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252000, Peoples R China

[2] Zhejiang Univ, Dept Chem, Xi Xi Campus, Hangzhou 310028, Zhejiang, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2016年 / 32卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Copper-catalyzed N-arylation; N-Arylimidazole; Ullmann-type coupling; ULLMANN COUPLING REACTION; BOND-FORMING REACTIONS; ARYL HALIDES; C-N; AMINATION REACTIONS; AMINO-ACIDS; COPPER; BROMIDES; NUCLEOPHILES; COMPLEX;

D O I：

10.1007/s40242-016-6263-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Employing 1,1'-binaphthyl-2,2'-diamine(BINAM) dihydrochloride as an efficient and commercially available ligand, relatively mild and highly efficient copper-catalyzed coupling reactions of imidazole with aryl and heteroaryl halides have been developed. Various N-arylimidazoles could be synthesized in moderate to excellent yields.

引用

页码：947 / 951

页数：5

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