Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene

被引：15
|
作者：
Xu, Qi [1 ]
Wang, Chu [1 ]
Zhao, Yu [2 ]
Zheng, Dan [1 ]
Shao, Chengyuan [1 ]
Guo, Weijie [1 ]
Deng, Xuebin [1 ]
Wang, Ying [1 ]
Chen, Xuebo [1 ]
Zhu, Jun [2 ]
Jiang, Hua [1 ]
机构：
[1] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China
[2] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Fujian Prov Key Lab Theoret & Computat Chem,Coll, Xiamen 361005, Peoples R China
来源：
ORGANIC LETTERS | 2020年 / 22卷 / 18期
基金：
中国国家自然科学基金;
关键词：
WARPED NANOGRAPHENE; CHARGE-TRANSPORT; PI-SYSTEMS; BOWL; DERIVATIVES; DELOCALIZATION; PRECURSOR; TOPOLOGY; HELICENE; PACKING;
D O I：
10.1021/acs.orglett.0c02754
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The selective fusions with pyrene derivative to the rim and flank bonds of corannulene generated 4 and 7, respectively, which underwent a Scholl reaction to provide novel distorted PAHs CORA-1 and CORA-2, consisting of corannulene and dibenzocoronene units with different connections between them. The studies revealed that the properties of these PAHs are highly dependent on the fusing positions of corannulene.
引用
收藏
页码：7397 / 7402
页数：6
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