Electrocatalytic Oxidation of Methanol on Nickel Doped Metal-Organic Frameworks MIL-110 Modified Glassy Carbon Electrode in Alkaline Medium

被引：12

作者：

Wang, Yan ^{[1
]}

Liu, Chenglian ^{[1
]}

Xiang, Jiangnan ^{[1
]}

Xing, Lei ^{[2
]}

Ou, Xiaoyu ^{[1
]}

Chen, Shili ^{[1
]}

Xue, Xiaojun ^{[1
]}

Yu, Feng ^{[1
]}

Li, Ruifeng ^{[1
]}

机构：

[1] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Shanxi, Peoples R China

[2] Jiangsu Univ, Inst Green Chem & Chem Technol, Zhenjiang 212013, Jiangsu, Peoples R China

来源：

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2019年 / 14卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Alkaline medium; Glassy Carbon Electrode; Metal-organic Frameworks; Methanol Electrooxidation; OXYGEN REDUCTION; FUEL-CELLS; NI; ELECTROOXIDATION; NANOPARTICLES; BEHAVIOR;

D O I：

10.20964/2019.06.11

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Nickel doped metal-organic frameworks MIL-110 catalysts were prepared by impregnation method. The as-prepared Ni/MIL-110 catalysts with different Ni content (10 wt.%, 20 wt.% and 30 wt.%) were characterized by XRD, SEM, elemental distribution analysis, N-2 adsorption-desorption and TEM. Ni/MIL-110 modified glassy carbon electrodes were employed to investigate the methanol electrooxidation reaction (MOR) in 0.1 M NaOH by cyclic voltammetry (CV) and chronoamperometry (CA). Ni/MIL-110 shows good electrocatalytic acidity toward MOR and MOR reaction is under diffusion controlled. And the catalytic rate constant is calculated to be 0.96 x 10(3)cm(3) mol(-1) s(-1) by CA analysis.

引用

页码：5247 / 5258

页数：12

共 50 条

[1] Electrocatalytic oxidation of methanol at a nickel hydroxide/glassy carbon modified electrode in alkaline medium
El-Shafei, AA
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 471 (02): : 89 - 95
[2] Electrocatalytic oxidation of methanol on the nickel-cobalt modified glassy carbon electrode in alkaline medium
Asgari, Mehdi
Maragheh, Mohammad Ghannadi
Davarkhah, Reza
Lohrasbi, Elaheh
Golikand, Ahmad Nozad
[J]. ELECTROCHIMICA ACTA, 2012, 59 : 284 - 289
[3] Electrocatalytic oxidation of methanol on a nickel-porphyrin IX complex modified glassy carbon electrode in alkaline medium
Golabi, SM
Nozad, A
[J]. ELECTROANALYSIS, 2004, 16 (03) : 199 - 209
[4] Electrocatalytic oxidation of methanol on a nickel electrode modified by nickel dimethylglyoxime complex in alkaline medium
Golikand, AN
Shahrokhian, S
Asgari, M
Maragheh, MG
Irannejad, L
Khanchi, A
[J]. JOURNAL OF POWER SOURCES, 2005, 144 (01) : 21 - 27
[5] Poly(1-Naphthylamine)-Nickel Modified Glassy Carbon Electrode for Electrocatalytic Oxidation of Formaldehyde in Alkaline Medium
Liu, Yuxia
[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2013, 8 (04): : 4776 - 4784
[6] A study of the electrocatalytic oxidation of methanol on a nickel-salophen-modified glassy carbon electrode
Raoof, Jahan Bakhsh
Golikand, Ahmad Nozad
Baghayeri, Mehdi
[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (05) : 817 - 822
[7] A study of the electrocatalytic oxidation of methanol on a nickel–salophen-modified glassy carbon electrode
Jahan Bakhsh Raoof
Ahmad Nozad Golikand
Mehdi Baghayeri
[J]. Journal of Solid State Electrochemistry, 2010, 14 : 817 - 822
[8] Electrocatalytic Oxidation of Methanol on NiMnsalpnY Modified Glassy Carbon Electrode
Hua, Xia
Gao, Zhihong
Wang, Yan
Wang, Wenyang
Wang, Baocheng
Li, Ruifeng
[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2019, 14 (08): : 8141 - 8160
[9] Electrocatalytic oxidation of methanol on NiZnsalenA modified glassy carbon electrode
Wenyang Wang
Ruifeng Li
Lu Liu
Rong Zhang
Baocheng Wang
[J]. Journal of Solid State Electrochemistry, 2015, 19 : 2001 - 2012
[10] Electrocatalytic oxidation of methanol on NiZnsalenA modified glassy carbon electrode
Wang, Wenyang
Li, Ruifeng
Liu, Lu
Zhang, Rong
Wang, Baocheng
[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2015, 19 (07) : 2001 - 2012

← 1 2 3 4 5 →