Application of the Preferential Solvation Viscosity Model to Binary Liquid Mixtures: Aqueous, Nonaqueous, Ionic Liquid, and Deep Eutectic Solvent Systems

被引：5
|
作者：
Duereh, Alif [1 ]
Sato, Yoshiyuki [1 ]
Smith, Richard Lee, Jr. [1 ,2 ]
Inomata, Hiroshi [1 ]
机构：
[1] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Grad Sch Engn, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
[2] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Grad Sch Environm Studies, Aoba Ku, Aramaki Aza Aoba 6-6-11, Sendai, Miyagi 9808579, Japan
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 32期
关键词：
EXCESS MOLAR VOLUMES; TEMPERATURE-RANGE; 293.15; HYDROGEN-BOND DONOR; PHYSICAL-PROPERTIES; REFRACTIVE-INDEX; GAMMA-VALEROLACTONE; TERNARY MIXTURES; 298.15; K; PHYSICOCHEMICAL PROPERTIES; DYNAMIC VISCOSITIES;
D O I：
10.1021/acs.iecr.9b01179
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The preferential solvation (PS) viscosity model was used to correlate binary liquid viscosities of aqueous, nonaqueous, nonpolar-polar, molecular solvent-ionic liquid (IL), and molecular solvent-deep eutectic solvent mixtures for the purpose of determining local composition in the chemical systems and analysis of chemical phenomena. Lignin solubility in aqueous systems was directly proportional to the population of (1-2) complex molecules. Cellulose solubility in molecular solvent-IL mixtures was directly proportional to the population of (2-2) associated molecules. Local compositions determined from the PS viscosity model were able to be used to estimate mixture solvent polarity and the variation of carbazole selectivity in crude anthracene separations. The PS viscosity model applied to chromatography allowed estimation of appropriate bulk composition regions for separations. Local compositions determined from the PS viscosity model can be used to analyze a wide variety of chemical phenomena in liquid solvent mixtures.
引用
收藏
页码：14991 / 15002
页数：12
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