First, we show the equivalence of two definitions of the left Riemann-Liouville fractional integral on time scales. Then, we establish and characterize fractional Sobolev space with the help of the notion of left Riemann-Liouville fractional derivative on time scales. At the same time, we define weak left fractional derivatives and demonstrate that they coincide with the left Riemann-Liouville ones on time scales. Next, we prove the equivalence of two kinds of norms in the introduced space and derive its completeness, reflexivity, separability, and some embedding. Finally, as an application, by constructing an appropriate variational setting, using the mountain pass theorem and the genus properties, the existence of weak solutions for a class of Kirchhoff-type fractional p-Laplacian systems on time scales with boundary conditions is studied, and three results of the existence of weak solutions for this problem is obtained.