Kinetics and mechanism of photochemical hydrolysis of enolpyruvic acid phosphoric ester

被引：0

作者：

Yasnikov, AA ^{[1
]}

Kanivets, NP ^{[1
]}

Samus, NV ^{[1
]}

Lozinskaya, OM ^{[1
]}

Markovsky, AL ^{[1
]}

机构：

[1] NATL ACAD SCI UKRAINE,INST BIOORGAN & COAL CHEM,UA-253094 KIEV 94,UKRAINE

来源：

TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA | 1996年 / 32卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It was found that phosphoric ester of enolpyruvic acid when excited by UV-light at 20 degrees C losts its phosphoryl group under participation of acids and bases. Increasing of temperature up to 50 degrees C causes the dissociation of fotoexcited molecule into enolpyruvate and metaphosphate, which in its turn phosphorylates ions HPO42-, H2P2O72- and AMP.

引用

页码：287 / 290

页数：4

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