SYNTHESIS AND CHARACTERIZATION OF FULLERENE-PYRIDYL ARENE RUTHENIUM COMPLEXES

被引：0

作者：

Appavoo, Divambal ^{[1
]}

Deschenaux, Robert ^{[1
]}

Therrien, Bruno ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, Ave Bellevaux 51, CH-2000 Neuchatel, Switzerland

来源：

STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA | 2015年 / 60卷 / 04期

基金：

瑞士国家科学基金会;

关键词：

fullerene; arene ligand; ruthenium; pyridyl ligand; half-sandwich complexes; MOLECULAR-STRUCTURE; ANTICANCER ACTIVITY; SOLAR-CELLS; C-60; DERIVATIVES; CATALYSIS; FULLEROPYRROLIDINES; METALLACYCLES; FERROCENE; CHEMISTRY;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (N-pyr-C-60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two half-sandwich complexes of the general formula (p-cymene)RuCl2(N-pyr-C-60). The coordination of the fullerenopyrrolidines to the arene ruthenium unit was evidenced by NMR spectroscopy and mass spectrometry, thus confirming the formation of these novel arene ruthenium complexes.

引用

页码：229 / 238

页数：10

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