Dispersion polymerization of vinylidene fluoride in supercritical carbon dioxide

被引：31
|
作者：
Mueller, Philipp A.
Storti, Giuseppe
Morbidelli, Massimo [1 ]
Costa, Ivano
Galia, Alessandro
Scialdone, Onofrio
Filardo, Giuseppe
机构：
[1] Swiss Fed Inst Technol, ETHZ Inst Chem & Bioingenieurwissensch, HCI, ETH Honggerberg, CH-8093 Zurich, Switzerland
[2] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, I-90128 Palermo, Italy
来源：
MACROMOLECULES | 2006年 / 39卷 / 19期
关键词：
D O I：
10.1021/ma060981l
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The dispersion polymerization of vinylidene fluoride in supercritical carbon dioxide is investigated using two ammonium carboxylate perfluoropolyether stabilizers of different molecular weights. Under suitable operating conditions a polymer made of well-dispersed spherical particles has been obtained up to relatively high conversion. The experimental data of polymerization rate and molecular weight distribution are in good agreement with the predictions of a model previously developed. Such an agreement supports the conclusion that the polymerization kinetics is dominated by the interphase transport of the active radicals between the continuous phase and the polymer particles.
引用
收藏
页码：6483 / 6488
页数：6
相关论文
共 50 条
  • [1] Homogeneous phase polymerization of vinylidene fluoride in supercritical carbon dioxide
    Beuermann, Sabine
    Imran-Ul-Haq, Muhammad
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (23) : 5626 - 5635
  • [2] Modeling of vinylidene fluoride heterogeneous polymerization in supercritical carbon dioxide
    Mueller, PA
    Storti, G
    Morbidelli, M
    Apostolo, M
    Martin, R
    [J]. MACROMOLECULES, 2005, 38 (16) : 7150 - 7163
  • [3] Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: Modeling the rate of polymerization
    Charpentier, PA
    DeSimone, JM
    Roberts, GW
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (12) : 4588 - 4596
  • [4] Dispersion polymerization of vinylidene fluoride in supercritical carbon dioxide using a fluorinated graft maleic anhydride copolymer stabilizer
    Tai, H
    Wang, WX
    Howdle, SM
    [J]. MACROMOLECULES, 2005, 38 (05) : 1542 - 1545
  • [5] Polymerization of vinylidene fluoride with perfluoropolyether surfactants in supercritical carbon dioxide as a dispersing medium
    Galia, A
    Giaconia, A
    Scialdone, O
    Apostolo, M
    Filardo, G
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (08) : 2406 - 2418
  • [6] Polymerization of Vinylidene Difluoride in Supercritical Carbon Dioxide
    Beginn, Uwe
    Najjar, Reza
    Ellmann, Juergen
    Moeller, Martin
    [J]. CHEMIE INGENIEUR TECHNIK, 2011, 83 (09) : 1419 - 1442
  • [7] Continuous precipitation polymerization of vinylidene fluoride in supercritical carbon dioxide: Molecular weight distribution
    Saraf, MK
    Wojcinski, LM
    Kennedy, KA
    Gerard, S
    Charpentier, PA
    DeSimone, J
    Roberts, GW
    [J]. MACROMOLECULAR SYMPOSIA, 2002, 182 : 119 - 129
  • [8] Copolymerization of vinylidene fluoride with hexafluoropropylene in supercritical carbon dioxide
    Ahmed, TS
    DeSimone, JM
    Roberts, GW
    [J]. MACROMOLECULES, 2006, 39 (01) : 15 - 18
  • [9] Polymerization of vinylidene fluoride in supercritical carbon dioxide: Effects of poly(dimethylsiloxane) macromonomer on molecular weight and morphology of poly(vinylidene fluoride)
    Tai, HY
    Wang, WX
    Martin, R
    Liu, J
    Lester, E
    Licence, P
    Woods, HM
    Howdle, SM
    [J]. MACROMOLECULES, 2005, 38 (02) : 355 - 363
  • [10] Copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical carbon dioxide
    Tai, HY
    Wang, WX
    Howdle, SM
    [J]. MACROMOLECULES, 2005, 38 (22) : 9135 - 9142
12345