Unraveling the facile reproducible modeled approach for bifunctional catalytic decorated polydopamine coated sponge composite for hydrogen generation

被引:2
|
作者
Tariq, Muhammad [1 ,2 ]
Ali, Meesam [3 ]
Li, Yali [1 ,4 ]
Han, Jinli [1 ,5 ]
Ning, Fandi [1 ,4 ]
He, Lei [1 ]
Shen, Min [1 ]
Bai, Chuang [1 ,4 ]
Jin, Hanqing [1 ,4 ]
Zhou, Xiaochun [1 ,4 ]
机构
[1] Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Div Adv Nanomat, Suzhou 215123, Peoples R China
[2] Suzhou Foreign Language Sch, Int High Sch, Dept Chem, Suzhou, Jiangsu, Peoples R China
[3] Muhammad Nawaz Sharif Univ Engn & Technol, Dept Chem Engn, Multan, Pakistan
[4] Univ Sci & Technol China, Sch Nano Technol & Nano Bion, Hefei, Peoples R China
[5] Wuhan Univ, Coll Chem & Mol Sci, Minist Educ, Key Lab Biomed Polymers, Wuhan, Peoples R China
基金
中国博士后科学基金; 国家重点研发计划;
关键词
catalytic decoration; hydrogen generation; polydopamine; sodium borohydride; sponge; REDUCED GRAPHENE OXIDE; SODIUM-BOROHYDRIDE SOLUTION; SOLID-PHASE EXTRACTION; FUEL-CELL; LOW-COST; HYDROLYSIS; NI; NANOPARTICLES; EVOLUTION; PERFORMANCE;
D O I
10.1002/er.8660
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Continuous, flexible, and pure hydrogen (H2) gas supply to the portable, and compact shape proton exchange membrane fuel cells and other type of fuel cells is considered as one of the key factor to be solved for researchers. In this research study, we develop the facile strategy to synthesize the novel, multipurpose catalytic decorated polydopamine coated sponge (CDPCS) composite for continuous H-2 generation for a long period of time as well as storage of solution within the composite. We explore the most efficient, light weight, hydrophilic commercial sponge, that is, wood pulp sponge (WPS), and binder, that is, polydopamine (PDA). Decoration of platinum nano particles and using of sodium borohydride solution are carried out as a case study by using assynthesized CDPCS. Various characterization techniques such as scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller (BET) analysis and energy dispersive X-ray (EDX) analysis are successfully employed to confirm the presence and size of nano particles and successfully coating of PDA layer. Hydrogen production performance of CDPCS with respect to different mass contents of Pt nanoparticles, molar concentration of sodium borohydride and at different temperature is investigated in this research study. An 87% yield of hydrogen generation has been achieved with 18 mg contents of Pt nano particles and 3 M concentration of sodium borohydride at room temperature. We believe that our conducted research study with respect to novel, facile, reproducible designed CDPCS based composites will be highly promising to simplify the hydrogen generation system for rapidly developed portable and wearable electronic devices.
引用
收藏
页码:23615 / 23629
页数:15
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