Microwave-assisted facile synthesis of silver nanoparticles in aqueous medium and investigation of their catalytic and antibacterial activities

被引:39
|
作者
Joseph, Siby [1 ]
Mathew, Beena [2 ]
机构
[1] St Georges Coll, Dept Chem, Kottayam 686122, Kerala, India
[2] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India
关键词
Microwave; Silver nanoparticle; Agar; Hexamine; Methyl orange; Catalysis; GREEN SYNTHESIS; REDUCTION;
D O I
10.1016/j.molliq.2014.06.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple, fast, efficient and cost effective synthetic strategy based on microwave irradiation is described for the preparation of silver nanoparticles in aqueous medium using hexamine as the reducing agent and agar as the stabilizer. The formation of nanoparticles is confirmed using UV-vis., XRD, EDX, and HR-TEM analysis. TEM images suggest that the nanoparticles are of spherical shape with an average diameter of 10.16 nm. The agar stabilized silver nanoparticles show excellent catalytic activity for the reduction of methyl orange in the presence of NaBH4 in aqueous medium. The reaction follows pseudo-first order kinetics, and the reaction rate increases with increase in amount of the catalyst. The synthesized silver nanoparticles are expected to be promising material for the application in environmental protection. They also show very good antibacterial activity against Staphylococcus aureus (Gram positive) and Salmonella typhi (Gram negative). (C) 2014 Elsevier B.V. All lights reserved.
引用
收藏
页码:346 / 352
页数:7
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