Synthesis, structural characterization and properties of new N-heterocyclic carbene Ag(I) complexes

被引：18

作者：

Kishore, Ravada ^{[1
]}

Das, Samar K. ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1053卷

关键词：

NHC-silver complexes; Structural elucidation; Supramolecular interactions; Spectroscopy; TRANSITION-METAL-COMPLEXES; COUPLING REACTIONS; SILVER(I)-CARBENE COMPLEXES; PHOTOPHYSICAL PROPERTIES; LIGANDS; CATALYSTS; SILVER; PALLADIUM(II); IMIDAZOL-2-YLIDENE; DIAMINOCARBENE;

D O I：

10.1016/j.molstruc.2013.08.051

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The syntheses and properties of new N-heterocyclic carbene complexes [{1-(2,3,5,6-tetra methyl benzyl)-3-benzylbimy}AgCl] (2a), 1{1-(benzyl)-3-benzylbimy}(2)Ag][BF4] (2b), [{1-(benzyl)-3-butylbimy}AgBr](2) (2c), [{1-(benzyl)-3-(4-nitro-benzyl)bimy}AgBr] (2d), [{1-(benzyl)-3-(4-bromo-benzyl)bimy)AgBr] (2e), [{1-(benzyl)-3-(4-nitro-benzyl)bimy}(2)Ag][BF4] (2f), [{1-(benzyl)-3-(4-bromo-benzyl)bimy](2)Ag][BF4] (2g) (bimy = benzimidazol-2-ylidene), and [{1-(10-bromo-9-anthracenylmethyl)-3-butylimy)AgBr] (2h) (imy = imidazol-2-ylidene) have been described. Compounds 2a-2h have been characterized by H-1 NMR-, UV-vis- LC/MS-spectral studies and elemental analysis. Compounds 2a-2c and 2h are unambiguously characterized by single crystal X-ray crystallography. Compound 2h shows solution emission at room temperature. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：38 / 47

页数：10

共 50 条

[1] Synthesis and structural characterization of N-heterocyclic carbene gold(I) complexes
de Frémont, P
Scott, NM
Stevens, ED
Nolan, SP
[J]. ORGANOMETALLICS, 2005, 24 (10) : 2411 - 2418
[2] N-Heterocyclic Carbene Complexes of Copper(I) Thiocyanate: Synthesis and Structural Characterization
Dodds, Christopher A.
Kennedy, Alan R.
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (05): : 926 - 930
[3] Silver(I) N-heterocyclic carbene complexes: Synthesis, characterization and cytotoxic properties
Gurbuz, Nevin
Kaloglu, Nazan
Kizrak, Umran
Ozdemir, Ilknur
Turkmen, Nese Basak
Ciftci, Osman
Ozdemir, Ismail
Mansour, L.
Naceur, Hamdi
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 923
[4] Ag(I) N-heterocyclic carbene complexes: Synthesis, structure, and application
Garrison, JC
Youngs, WJ
[J]. CHEMICAL REVIEWS, 2005, 105 (11) : 3978 - 4008
[5] Synthesis and structural characterization of two novel N-heterocyclic carbene complexes of Rh(I)
Karabiyik, Hasan
Kilincarslan, Rafet
Aygun, Muhittin
Cetinkaya, Bekir
Buyukgungor, Orhan
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (04) : 393 - 399
[6] Synthesis and structural characterization of N-heterocyclic carbene complexes of silver(I) and rhodium(I) from caffeine
Kascatan-Nebioglu, A
Panzner, MJ
Garrison, JC
Tessier, CA
Youngs, WJ
[J]. ORGANOMETALLICS, 2004, 23 (08) : 1928 - 1931
[7] Rhodium(i) N-heterocyclic carbene complexes: synthesis and cytotoxic properties
Slimani, Ichraf
Sahin-Bolukbasi, Serap
Ulu, Mustafa
Evren, Enes
Gurbuz, Nevin
Ozdemir, Ilknur
Hamdi, Naceur
Ozdemir, Ismail
[J]. NEW JOURNAL OF CHEMISTRY, 2021, 45 (11) : 5176 - 5183
[8] Novel N-heterocyclic carbene silver(I) complexes: Synthesis, structural characterization, and anticancer activity
Bolukbasi, Serap Sahin
Sahin, Neslihan
Tahir, Muhammad Nawaz F.
Arici, Cengiz
Cevik, Esranur
Gurbuz, Nevin
Ozdemir, Ismail
Cummings, Brian S.
[J]. INORGANICA CHIMICA ACTA, 2019, 486 : 711 - 718
[9] Preparation and application of N-heterocyclic carbene complexes of Ag(I)
Lin, Ivan J. B.
Vasam, Chandra Sekhar
[J]. COORDINATION CHEMISTRY REVIEWS, 2007, 251 (5-6) : 642 - 670
[10] Synthesis and characterization of Ag(I) and Au(I) complexes with macrocyclic hybrid amine N-heterocyclic carbene ligands
Lu, Taotao
Yang, Chu-Fan
Steren, Carlos A.
Fei, Fan
Chen, Xue-Tai
Xue, Zi-Ling
[J]. NEW JOURNAL OF CHEMISTRY, 2018, 42 (06) : 4700 - 4713

← 1 2 3 4 5 →