Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(II)-polypyridine complexes with phenolate ions

被引：46
|
作者：
Thanasekaran, P
Rajendran, T
Rajagopal, S
Srinivasan, C
Ramaraj, R
Ramamurthy, P
Venkatachalapathy, B
机构：
[1] MADURAI KAMARAJ UNIV,SCH CHEM,MADURAI 625021,TAMIL NADU,INDIA
[2] MADURAI KAMARAJ UNIV,DEPT MAT SCI,MADURAI 625021,TAMIL NADU,INDIA
[3] UNIV MADRAS,DEPT INORGAN CHEM,MADRAS 600025,TAMIL NADU,INDIA
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 44期
关键词：
D O I：
10.1021/jp971746v
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ruthenium(II)-polypyridyl complexes of similar size but with variable reduction potential undergo efficient photoinduced electron-transfer reactions with phenolate ions in aqueous medium. All these reactions are exergonic and are in accordance with the Marcus theory of electron transfer. At high negative Delta G(o) Marcus inverted region is observed in this bimolecular photoinduced charge separation reaction.
引用
收藏
页码：8195 / 8199
页数：5
相关论文
共 50 条
  • [1] Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(II)-polypyridine complexes with phenolate ions
    Madurai Kamaraj Univ, Madurai, India
    J Phys Chem A, 44 (8195-8199):
  • [2] Comment on "Marcus inverted region in the photoinduced electron transfer reactions of ruthenium(II)-polypyridine complexes with phenolate ions"
    Li, C
    Hoffman, MZ
    JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (29): : 6052 - 6053
  • [3] Effect of Sodium Dodecyl Sulfate on the Photoinduced Electron Transfer Reactions of Ruthenium(II)-Polypyridine Complexes with Phenolate Ions
    Rajendran, T.
    Rajagopal, S.
    Srinivasan, C.
    Balakrishnan, G.
    Sivasubramanian, V. K.
    Ganesan, M.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (10) : 2074 - 2082
  • [4] Effect of Sodium Dodecyl Sulfate on the Photoinduced Electron Transfer Reactions of Ruthenium(II)–Polypyridine Complexes with Phenolate Ions
    T. Rajendran
    S. Rajagopal
    C. Srinivasan
    G. Balakrishnan
    V. K. Sivasubramanian
    M. Ganesan
    Russian Journal of Physical Chemistry A, 2021, 95 : 2074 - 2082
  • [5] Steric effects in the photoinduced electron transfer reactions of ruthenium(II)-polypyridine complexes with 2,6-disubstituted phenolate ions
    Rajendran, T
    Thanasekaran, P
    Rajagopal, S
    Gnanaraj, GA
    Srinivasan, C
    Ramamurthy, P
    Venkatachalapathy, B
    Manimaran, B
    Lu, KL
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (11) : 2063 - 2069
  • [6] INTRAMOLECULAR ELECTRON-TRANSFER IN CYTOCHROME-B(5) LABELED WITH RUTHENIUM(II) POLYPYRIDINE COMPLEXES - RATE MEASUREMENTS IN THE MARCUS INVERTED REGION
    SCOTT, JR
    WILLIE, A
    MCLEAN, M
    STAYTON, PS
    SLIGAR, SG
    DURHAM, B
    MILLETT, F
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) : 6820 - 6824
  • [7] Ruthenium(II) polypyridine complexes and the electron-transfer reactions of metalloproteins
    Durham, B
    Millett, F
    JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (06) : 636 - 640
  • [8] Micellar effect on the photoinduced electron-transfer reactions of ruthenium(II)-polypyridyl complexes with phenolate ions. Effect of cetyltrimethylammonium chloride
    Rajendran, T
    Rajagopal, S
    Srinivasan, C
    Ramamurthy, P
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (17): : 3155 - 3160
  • [9] Photoinduced Energy and Electron-Transfer Reactions by Polypyridine Ruthenium(II) Complexes Containing a Derivatized Perylene Diimide
    dos Santos, Edjane R.
    Pina, Joao
    Venancio, Tiago
    Serpa, Carlos
    Martinho, Jose M. G.
    Carlos, Rose Maria
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (40): : 22831 - 22843
  • [10] PHOTOINDUCED ELECTRON-TRANSFER REACTIONS BETWEEN DICYANOBIS(POLYPYRIDINE)RUTHENIUM(II) AND TRIS(BETA-DIKETONATO)RUTHENIUM(III) COMPLEXES
    MARUYAMA, M
    SONOYAMA, N
    KAIZU, Y
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (20): : 5332 - 5337
12345