Recent Progress in Preparation of Functionalized Organometallics

被引：0
|
作者：
Nakae, Takahiro
机构：
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2009年 / 67卷 / 04期
关键词：
DIRECT INSERTION; MAGNESIUM EXCHANGE; BENZYLIC ZINC; ARYL; REAGENTS; INDIUM; ORGANOSTANNANES; HALOGEN; IODIDES;
D O I：
10.5059/yukigoseikyokaishi.67.395
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Preparation of functionalized organometallic reagents is widely used in organic synthesis. Convenient, practical, and economical methods for preparation of functionalized organometallics were highly demanded. Recently, Knochel et al. reported direct metal insertion into carbon-halogen bond was dramatically promoted in the presence of lithium chloride. This method was applicable to prepare organozinc, -magnesium, and -indium reagents.
引用
收藏
页码：395 / 396
页数：2
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