Investigating the Condensation of Benzene (C6H6) in Titan's South Polar Cloud System with a Combination of Laboratory, Observational, and Modeling Tools

We have combined laboratory, modeling, and observational efforts to investigate the chemical and microphysical processes leading to the formation of the cloud system that formed at an unusually high altitude (>250 km) over Titan's south pole after the northern spring equinox. We present here a study focused on the formation of C6H6 ice clouds at 87 degrees S. As the first step of our synergistic approach, we have measured, for the first time, the equilibrium vapor pressure of pure crystalline C6H6 at low temperatures (134-158 K) representative of Titan's atmosphere. Our laboratory data indicate that the experimental vapor pressure values are larger than those predicted by extrapolations found in the literature calculated from higher-temperature laboratory measurements. We have used our experimental results along with temperature profiles and C6H6 mixing ratios derived from observational data acquired by the Cassini Composite Infrared Spectrometer (CIRS) as input parameters in the coupled microphysics radiative transfer Community Aerosol and Radiation Model for Atmospheres (CARMA). CARMA simulations constrained by these input parameters were conducted to derive C6H6 ice particle size distribution, gas volume mixing ratios, gas relative humidity, and cloud altitudes. The impact of the vapor pressure on the CIRS data analysis and in the CARMA simulations was investigated and resulted in both cases in benzene condensation occurring at lower altitude in the stratosphere than previously thought. In addition, the stratospheric C6H6 gas abundances predicted with the new saturation relationship are similar to 1000x higher than previous calculations between 150-200 km, which results in larger particle sizes.