DNA-Binding Spectra Studies of Complex Ce(III) with 2-Thenoyltrifluoroacetone-Piperidine Ligands

被引：0

作者：

Zhang Gai-Qing ^{[1
,2
]}

Yin Cai-Xia ^{[1
]}

Huo Fang-Ju ^{[3
]}

Wu Yan-Bo ^{[1
]}

Yang Pin ^{[1
]}

机构：

[1] Shanxi Univ, Inst Mol Sci, Key Lab Chem Biol & Mol Engn MOE, Taiyuan 030006, Peoples R China

[2] Luliang Teachers Coll, Dept Chem, Luliang 033000, Shanxi, Peoples R China

[3] Shanxi Univ, Res Inst Appl Chem, Taiyuan 030006, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 03期

关键词：

2-thenoyltrifluoroacetone-piperidine Ce(III); complex; crystal structure; spectra; DNA-binding properties; RUTHENIUM(II); INTERCALATOR;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A kind of Ce (III) complex with TTA(4)center dot HP (TTA =2-Thenoyltrifluoroacetone, HP =Piperidine) has been synthesized and characterized. DNA-binding properties of CeTTA(4)center dot HP were investigated using UV spectra, fluorescent spectra, thermal denaturation, CV(cyclic voltammetry), viscometry and molecular modeling. The results showed that the binding-mode between CeTTA(4)center dot HP and DNA is intercalation.

引用

页码：428 / 432

页数：5

共 29 条

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