Simple Copper(II) Schiff Base Complex as Efficient Heterogeneous Photo-Fenton-like Catalyst

被引：4
|
作者：
Fei, Bao-Li [1 ,2 ]
Wang, Jiang-Hong [1 ]
Yan, Qing-Ling [1 ]
Liu, Qing-Bo [3 ]
Long, Jian-Ying [3 ]
Li, Yang-Guang [4 ]
Shao, Kui-Zhan [4 ]
Su, Zhong-Min [4 ]
Sun, Wei-Yin [2 ]
机构：
[1] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China
[2] Nanjing Univ, Coordinat Chem Inst, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Forestry Univ, Coll Sci, Nanjing 210037, Jiangsu, Peoples R China
[4] NE Normal Univ, Fac Chem, Inst Funct Mat Chem, Changchun 130024, Peoples R China
来源：
CHEMISTRY LETTERS | 2014年 / 43卷 / 07期
关键词：
DYES; DECOLORIZATION; DEGRADATION; OXIDATION;
D O I：
10.1246/cl.140147
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The efficient photocatalytic degradation of methyl orange was achieved by exploring two simple copper(II) Schiff base complexes [{Cu(HL)(CH3OH)}(2)] (1) and [Cu(HL)(2)] (2) (H2L = N-salicylidene-2-aminoethanol) as photo-Fenton-like catalysts. Both 1 and 2 exhibited excellent catalytic performance without an acidification process, and the mononuclear complex 2 functioned better than the dinuclear complex 1. The results suggest that 2 is advantageous for catalyzing efficient degradation of azo dye and has potential application in the effective treatment of dye-polluted water.
引用
收藏
页码：1158 / 1160
页数：3
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