Graphene, charcoal, ZnO, and ZnS/BiOX (X = Cl, Br, and I) hybrid microspheres for photocatalytic simulated real mixed dye treatments

被引:41
|
作者
Yoon, Hee Jung [1 ]
Choi, Young In [1 ]
Jang, Eue-Soon [2 ]
Sohn, Youngku [1 ]
机构
[1] Yeungnam Univ, Dept Chem, Gyongsan 38541, South Korea
[2] Kumoh Natl Inst Technol, Dept Appl Chem, Gyeongbuk 39177, South Korea
基金
新加坡国家研究基金会;
关键词
BiOX; ZnS/ZnO; Graphene/charcoal; Mixed dye; Photocatalytic dye degradation; P-N-JUNCTION; ONE-STEP SYNTHESIS; SOLVOTHERMAL SYNTHESIS; BIOCL NANOSHEETS; BIOI/BIOCL COMPOSITES; TEMPERATURE SYNTHESIS; ARRAY HETEROJUNCTION; PHENOL DEGRADATION; METHYL-ORANGE; IONIC LIQUID;
D O I
10.1016/j.jiec.2015.08.010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene, charcoal, ZnO, and ZnS/BiOX (X = Cl, Br, and I) hybrid microspheres were synthesized for use in the photocatalytic treatment of a mixed dye of MO (methyl orange), RhB (rhodamine B), and MB (methylene blue) solution. The dye degradation rate was generally observed in the order of RhB < MB < MO. The order became MB < RhB < MO for ZnO/BiOI and ZnS/BiOI. The catalysts hybridized with BiOI generally showed superior adsorption capacity to those of the materials hybridized with BiOCI or BiOBr. The 10 mol% ZnO/BiOI and ZnS/BiOI showed selectivity for MB adsorption in the mixed dye. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:137 / 152
页数:16
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