GAMMA-RAY IRRADIATION-INDUCED IMPROVEMENT OF HYDROGEN ADSORPTION IN MULTI-WALLED CARBON NANOTUBES

被引：15
|
作者：
Qian, Wen [1 ]
Chen, Jiafu [1 ]
Wei, Lingzhi [1 ]
Wu, Liusuo [1 ]
Chen, Qianwang [1 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
来源：
NANO | 2009年 / 4卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Carbon nanotube; defect; hydrogen adsorption; irradiation effects; physisorption and chemisorption; STORAGE; PURIFICATION; GRAPHITE;
D O I：
10.1142/S1793292009001459
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
An improved hydrogen adsorption capacity of 0.5-0.6 wt% was obtained at room temperature and 10.0 MPa pressure for commercial MWNT sample by gamma-ray irradiation, compared with 0.33 wt% of pristine MWNTs. The irradiation-induced defects in structure, which is favorable for hydrogen adsorption, were characterized by ESR spectrum, elemental analysis, and Raman spectrum. The results show that gamma-ray irradiation increased the hydrogen adsorption capacity due to the increasing number of defects created by gamma-photons, but would reach the maximum when defect concentration achieves saturation.
引用
收藏
页码：7 / 11
页数：5
相关论文
共 50 条
  • [1] The effect of gamma ray irradiation on the structure of graphite and multi-walled carbon nanotubes
    Li, Bin
    Feng, Yi
    Ding, Kewang
    Qian, Gang
    Zhang, Xuebin
    Zhang, Jingcheng
    [J]. CARBON, 2013, 60 : 186 - 192
  • [2] Gamma (γ)-ray irradiated multi-walled carbon nanotubes (MWCNTs) for hydrogen storage
    Silambarasan, D.
    Surya, V. J.
    Iyakutti, K.
    Asokan, K.
    Vasu, V.
    Kawazoe, Y.
    [J]. APPLIED SURFACE SCIENCE, 2017, 418 : 49 - 55
  • [3] Electron irradiation-induced change of structure and damage mechanisms in multi-walled carbon nanotubes
    Yang Jian-Qun
    Li Xing-Ji
    Liu Chao-Ming
    Ma Guo-Liang
    Gao Feng
    [J]. CHINESE PHYSICS B, 2015, 24 (11)
  • [4] Electron irradiation-induced change of structure and damage mechanisms in multi-walled carbon nanotubes
    杨剑群
    李兴冀
    刘超铭
    马国亮
    高峰
    [J]. Chinese Physics B, 2015, (11) : 337 - 345
  • [5] Structural Ordering of Multi-walled Carbon Nanotubes (MWCNTs) Caused by Gamma (γ)-ray Irradiation
    Silambarasan, D.
    Iyakutti, K.
    Asokan, K.
    Vasu, V.
    [J]. PROCEEDINGS OF THE 59TH DAE SOLID STATE PHYSICS SYMPOSIUM 2014 (SOLID STATE PHYSICS), 2015, 1665
  • [6] Gamma and neutron irradiation effects on multi-walled carbon nanotubes
    Akbaba, Ugur
    Kasapoglu, Ahmet Emre
    Gur, Emre
    [J]. DIAMOND AND RELATED MATERIALS, 2018, 87 : 242 - 247
  • [7] Hydrogen adsorption storage study on multi-walled carbon nanotubes
    Yao, Yunjin
    Zhang, Suping
    Yan, Yongjie
    [J]. Taiyangneng Xuebao/Acta Energiae Solaris Sinica, 2008, 29 (06): : 767 - 770
  • [8] Adsorption equilibrium of supercritical hydrogen on multi-walled carbon nanotubes
    Zheng, QR
    Gu, AZ
    Lu, XS
    Lin, WS
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 34 (01): : 71 - 79
  • [9] Characteristics of adsorption and desorption of hydrogen on multi-walled carbon nanotubes
    Zhou, ZH
    Wu, XM
    Wang, Y
    Lin, GD
    Zhang, HB
    [J]. ACTA PHYSICO-CHIMICA SINICA, 2002, 18 (08) : 692 - 698
  • [10] The effect of pretreatments on hydrogen adsorption of multi-walled carbon nanotubes
    Huang, WZ
    Zhang, XB
    Tu, JP
    Kong, FZ
    Ma, JX
    Liu, F
    Lu, HM
    Chen, CP
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (01) : 144 - 148
12345