Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers

被引：96
|
作者：
Ohtani, Ryo [1 ]
Hayami, Shinya [1 ,2 ]
机构：
[1] Kumamoto Univ, Grad Sch Sci & Technol, Dept Chem, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
[2] Kumamoto Univ, Inst Pulsed Power Sci, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 10期
关键词：
host-guest chemistry; metal-organic frameworks; porous coordination polymers; spin-state switching; spin transition; METAL-ORGANIC-FRAMEWORK; CROSSOVER BEHAVIOR; THERMAL HYSTERESIS; TEMPERATURE; MODULATION; ADSORPTION; CONDUCTIVITY; MOLECULES; COMPOUND; POROSITY;
D O I：
10.1002/chem.201601880
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The host-guest composites of Hofmann-type iron(II) spin-transition (ST) porous coordination polymers incorporating guest molecules show guest-dependent ST behavior in accordance with the respective guest species, which may be a gas, solvent, halogen, or organic molecule. The guest also works as a chemical stimulant to switch the spin state of the host between high and low spin at room temperature. In this review, we discuss guest properties including size, shape, flexibility, chemical properties, and pore loading content, which impact the spin states of the host framework and the ST behavior exhibited by the host-guest composites.
引用
收藏
页码：2236 / 2248
页数：13
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