Comment on "Non-symmetric substituted ureas locked in an (E,Z) conformation: an unusual anion binding via supramolecular assembly" by M. Olivari, C. Caltagirone, A. Garau, F. Isaia, M. E. Light, V. Lippolis, R. Montis and M. A. Scorciapino, New J. Chem., 2013, 37, 663

被引:7
|
作者
Osmialowski, Borys [1 ]
Kolehmainen, Erkki [2 ]
机构
[1] Univ Technol & Life Sci, Fac Chem Technol & Engn, PL-85326 Bydgoszcz, Poland
[2] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland
关键词
HYDROGEN-BOND; ASSOCIATION; COMPLEXATION; NMR;
D O I
10.1039/c3nj01282d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We propose another point of view on the type of hydrogen bonded complexes that were described in this journal (M. Olivari et at, New J. Chem., 2013, 37, 663). The main difference is the molecular geometry and breakage of the intramolecular hydrogen bond during association. The current comment is to highlight mentioned aspects and to point out that in some cases the interpretation may not be straightforward due to the simultaneous effects associated with complexation.
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页码:2701 / 2703
页数:3
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