Photochemistry via photoelectron spectroscopy: N-substituted phthalimides

被引：4
|
作者：
Novak, Igor
Kovac, Branka
机构：
[1] Charles Sturt Univ, Orange, NSW 2800, Australia
[2] Rudjer Boskovic Inst, Div Phys Chem, HR-10002 Zagreb, Croatia
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 2006年 / 110卷 / 25期
关键词：
D O I：
10.1021/jp057269v
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electronic structures of several N-substituted phthalimides have been investigated by UV photoelectron spectroscopy and outer valence Greens function calculations. Some spectra reveal the presence of photofragmentation and photoelimination processes related to the decay of the aminium radical cation. We compared the fragmentation mechanisms in the gas phase and in the solution.
引用
收藏
页码：7772 / 7776
页数：5
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